Product ID:PERMABOND QFS 1, 78-4336
MSDS Date:01/14/1993
FSC:8040
NIIN:00N044984
MSDS Number: BTWXL

NATIONAL STARCH AND CHEMICAL CO

FINDERNE AVENUE
BRIDGEWATER, NJ 08807
US

Emergency Phone: 908-685-5000

Info Phone: 908-685-5000

Preparer: E. SOETERIK

Cage: 85091

NATIONAL STARCH AND CHEMICAL CORP

6500 BRIDGEWATER, NJ 08807 US

Telephone: 908685-5306

Cage: 85091

0.4 LBS/GAL (45 G/L)

RTECS: 9999999VO

OSHA PEL N/K

ACGIH TLV: N/K

METHYL CHLOROFORM (1,1,1-TRICHLOROETHANE) (SARA III)

CAS: 71-55-6

RTECS: KJ2975000

Fraction By Weight: 99.1%

OSHA PEL 350 PPM; 450 STEL

ACGIH TLV: 350 PPM; 450 STEL

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

LD50 LC50 Mixture:LD50 (ORAL, RAT):10300 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:CHLOROCARBON MATLS HAVE PRDCED SENSIT
OF MYOCARDIUM TO EPINEPHRINE IN LAB ANIMALS & COULD HAVE SIMILAR
EFT IN HUMANS. ADRENOMIMETICS (EG, EPINEPHRINE) MAY BE
CONTRA-INDICATED EXCEPT FOR LIFE-SUSTAININ G USES IN HUMANS
ACUTELY/CHRONICALLY EXPOS TO CHLOROCARBONS . EYES:IRRIT & MAY
INJURE EYE TISS (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:IF NOT REMOVED PROMPTLY.
SKIN:RPTD/PRLNG CNTCT MAY CAUSE DEFAT WHICH MAY LEAD TO SKIN IRRIT
&/OR DRYNESS. INHAL:HIGH VAP CONC IRRIT TO EYES & RESP TRACT. MAY
CAUSE HDCH & DIZZ, ARE ANESTHETIC & MAY HAVE OTHER CNS EFTS.
INGEST:MOD TOX. 1,1,1,TRICHLOROETHANE IS EYE, MUC MEMB & SKIN IRRIT
& TOX CNS (SUPDAT)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:EYES:IMMED FLUSH W/LG AMT H*2O FOR @ LEAST 15 MIN, LIFTING
UPPER & LOWER LIDS. GET PROMPT MED ATTN. SKIN:FLUSH W/LG AMT H*2O.
USE SOAP IF AVAIL. REMOVE GROSSLY CONTAMD CLTHG, INCL SHOES &
LAUNDER BEFO RE REUSE. DISCARD SHOES. INHAL:MOVE TO FRESH AIR.
ADMIN O*2 TO AID BRTHG. GET MED ATTN. INGEST:INDUCE VOMIT ONLY IF
ALERT. GET PROMPT MED ATTN. DO NOT GIVE ANYTHING BY MOUTH TO
DROWSY/UNCON PERSON.

Flash Point Method:TCC
Flash Point:>200F,>93C
Lower Limits:8%
Upper Limits:10.5%
Extinguishing Media:DRY CHEMICAL, CARBON DIOXIDE, ALCOHOL FOAM.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED PRESSURE DEMAND SCBA
AND FULL PROTECTIVE EQUIPMENT . COOL EXPOSED EQUIPMENT WITH WATER
SPRAY.
Unusual Fire/Explosion Hazard:THERMAL DECOMPOSITION PRODUCTS MAY
INCLUDE HCL AND PHOSGENE . NEGLIGIBLE FIRE HAZARD WHEN EXPOSED TO
HEAT OR FLAME.

Spill Release Procedures:SHUT OFF IGNIT SOURCES. STOP LEAK IF CAN DO
W/OUT RISK. FOR SMALL LIQ SPILLS, TAKE UP W/SAND/OTHER ABSORBENT
MATL. FOR LARGER SPILLS, DIKE FAR AHEAD OF SPILL FOR LATER DISP. NO
SMOKING, FLAMES OR FLAR ES IN HAZARD AREA! KEEP UNNEC PEOPLE AWAY.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:PROTECT FROM FREEZING. STORE AT
AMBIENT TEMPERATURES (40-90F).
Other Precautions:NO SMOKING IN AREA OF USE. DO NOT USE IN THE GENERAL
VICINITY OF ARC WELDING, OPEN FLAMES OR HOT SURFACES. HEAT AND/OR
UV RADIATION MAY CAUSE THE FORMATION OF HCL AND/OR PHOSGENE .

Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR IF REQUIRED.
NIOSH/MSHA APPROVED SELF-CONTAINED BREATHING APPARATUS IN EMERGENCY
AND NON-ROUTINE SITUATIONS.
Ventilation:LOCAL; GENERAL.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPVD CHEM WORK GOGG .
Other Protective Equipment:APPROPRIATE PROTECTIVE CLOTHING & EQUIPMENT
TO PREVENT ANY POSSIBILITY OF SKIN CONTACT WITH THIS SUBSTANCE.
Work Hygienic Practices:WASH HANDS BEFORE EATING/DRINKING/SMKNG/USING
REST ROOM FACILITIES. REMOVE & LAUNDER GROSSLY CONTAMD CLTHG BEFORE
REUSE.
Supplemental Safety and Health
EFTS OF OVEREXP:DEPRESS. POISONING MAY AFFECT HEART & POSS LIVER &
KIDNEYS. ALCOHOL MAY POTENTIATE BOTH CARDIAC & HEPATIC TOX.
CHRONIC:MINIMAL KIDNEY/LIVER DMG FROM LONG TERM INHAL OF AMTS >
TLV. NO E FTS KNOWN TO HUMANS FROM CHRONIC SKIN CNTCT, EYE
CNTCT/INGEST. TARGET ORGANS:CARDIOVASCULAR SYS, CNS, KIDNEYS,
LIVER.

Boiling Pt:B.P. Text:165F,74C
Melt/Freeze Pt:M.P/F.P Text:-36F,-38C
Vapor Pres:100 @ 20C
Vapor Density:4.6
Spec Gravity:1.330 (H*2O=1)
Evaporation Rate & Reference:>1 (WATER)
Solubility in Water:INSOLUBLE
Appearance and Odor:CLEAR LIQUID; CHLORINATED SOLVENT ODOR.
Percent Volatiles by Volume:99

Stability Indicator/Materials to Avoid:YES
CHEMICALLY ACTIVE METALS (ALUMINUM POWDER, SODIUM, POTASSIUM, MAGNESIUM
POWDER) & THEIR HYDROXIDES.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:HCL, PHOSGENE . CO, CO*2, CHLORINE
CMPDS, HYDROCARBONS OF INDETERMINATE NATURE (DEPENDING ON
CONDITIONS).

Waste Disposal Methods:WASTE DISPOSAL SHOULD BE IN ACCORDANCE WITH
EXISTING FEDERAL, STATE AND LOCAL EVNIRONMENTAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.